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Chemisorption solid materials for hydrogen storage near ambient temperature: a review

Yiheng ZHANG, Shaofei WU, Liwei WANG, Xuefeng ZHANG

《能源前沿（英文）》 2023年 第17卷 第1期   页码 72-101 doi: 10.1007/s11708-022-0835-7

摘要： Solid chemisorption technologies for hydrogen storage, especially high-efficiency hydrogen storage of fuel cells in near ambient temperature zone defined from −20 to 100°C, have a great application potential for realizing the global goal of carbon dioxide emission reduction and vision of carbon neutrality. However, there are several challenges to be solved at near ambient temperature, i.e., unclear hydrogen storage mechanism, low sorption capacity, poor sorption kinetics, and complicated synthetic procedures. In this review, the characteristics and modification methods of chemisorption hydrogen storage materials at near ambient temperature are discussed. The interaction between hydrogen and materials is analyzed, including the microscopic, thermodynamic, and mechanical properties. Based on the classification of hydrogen storage metals, the operation temperature zone and temperature shifting methods are discussed. A series of modification and reprocessing methods are summarized, including preparation, synthesis, simulation, and experimental analysis. Finally, perspectives on advanced solid chemisorption materials promising for efficient and scalable hydrogen storage systems are provided.

关键词： hydrogen storage capacity     chemisorption     near-ambient-temperature     modification methods     alloy hydrides    

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Evaluating the short-term effect of ambient temperature on non-fatal outdoor falls and road traffic injuries

《环境科学与工程前沿（英文）》 2023年 第17卷 第9期 doi: 10.1007/s11783-023-1705-1

摘要：

● A study assessing the temperature-injury relationship was conducted among students.

关键词： Ambient temperature     Fall     Road traffic injury     Student     China    

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Prediction of the theoretical and semi-empirical model of ambient temperature

Foued CHABANE,Noureddine MOUMMI,Abdelhafid BRIMA,Abdelhafid MOUMMI

《能源前沿（英文）》 2016年 第10卷 第3期   页码 268-276 doi: 10.1007/s11708-016-0413-y

摘要： It is well known that the ambient temperature is a sensitive parameter which has a great effect on biology, technology, geology and even on human behavior. A prediction is a statement about an uncertain event. It is often, but not always, based upon experience or knowledge. Although guaranteed accurate information about the future is in many cases impossible, prediction can be useful to assist in making plans about possible developments. As a result, temperature profiles can be developed which accurately represent the expected ambient temperature exposure that this environment experiences during measurement. The ambient temperature over time is modeled based on the previous and data and using a Lagrange interpolation. To observe the comprehensive variation of ambient temperature the profile must be determined numerically. The model proposed in this paper can provide an acceptable way to measure the change in ambient temperature.

关键词： ambient temperature     environment     correlation     theoretical model     semi-empirical    

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Effects of ambient temperature on regulated gaseous and particulate emissions from gasoline-, E10- and

Rencheng Zhu, Jingnan Hu, Liqiang He, Lei Zu, Xiaofeng Bao, Yitu Lai, Sheng Su

《环境科学与工程前沿（英文）》 2021年 第15卷 第1期 doi: 10.1007/s11783-020-1306-1

摘要： Abstract • Emissions from two sedans were tested with gasoline, E10 and M15 at 30°C and -7°C. • As the temperature decreased, the PM, PN and BC emissions increased with all fuels. • Particulate emissions with E10 and M15 were more sensitive to the temperature. • The PN and BC generated during cold start-up dominated those over the WLTC. Ambient temperature has substantial impacts on vehicle emissions, but the impacts may differ between traditional and alcohol gasolines. The objective of this study was to investigate the effects of temperature on gaseous and particulate emissions with both traditional and alcohol gasoline. Regulated gaseous, particle mass (PM), particle number (PN) and black carbon (BC) emissions from typical passenger vehicles were separately quantified with gasoline, E10 (10% ethanol and 90% gasoline by volume) and M15 (15% methanol and 85% gasoline by volume) at both 30°C and -7°C. The particulate emissions with all fuels increased significantly with decreased temperature. The PM emissions with E10 were only 48.0%–50.7% of those with gasoline at 30°C but increased to 59.2%-79.4% at -7°C. The PM emissions with M15 were comparable to those with gasoline at 30°C, but at -7°C, the average PM emissions were higher than those with gasoline. The variation trend of PN emissions was similar to that of PM emissions with changes in the fuel and temperature. At 30°C, the BC emissions were lower with E10 and M15 than with gasoline in most cases, but E10 and M15 might emit more BC than gasoline at -7°C, especially M15. The results of the transient PN and BC emission rates show that particulate emissions were dominated mainly by those emitted during the cold-start moment. Overall, the particulate emissions with E10 and M15 were more easily affected by ambient temperature, and the advantages of E10 and M15 in controlling particulate emissions declined as the ambient temperature decreased.

关键词： Particle mass     Particle number     Black carbon     Alcohol gasoline     Low temperature    

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Numerical investigation on side heat transfer enhancement in 300 kA aluminum reduction cell

WANG Changhong, ZHU Dongsheng, LEI Junxi, ZHOU Jiemin

《能源前沿（英文）》 2008年 第2卷 第3期   页码 256-260 doi: 10.1007/s11708-008-0051-0

摘要： Industrial test and numerical simulation were synchronously applied to analyze the side heat transfer process and enhance heat transfer in aluminum reduction cell. The 3D slice finite element model of aluminum reduction cell was developed, with which the sidewall temperature field of the cell was computed by using software ANSYS. The main influencing factors on heat dissipation were analyzed and some effective measures were proposed to enhance sidewall heat transfer. The results show that the shell temperature of the test cell and the common cell is respectively 312°C and 318°C and the ledge thickness is 16 cm and 15 cm when side coefficient of heat transfer between the shell and the surroundings is 70 W/(mK). With the increase of the side coefficient of heat transfer between the shell and the surroundings, the temperature of the shell decreases but the thickness of the side ledge increases when the electrolytic temperature, the ambient temperature, the coefficient of heat transfer between molten bath and ledge, the eutectic temperature and the thermo-resistance of the side lining are constant.

关键词： constant     ambient temperature     thickness     electrolytic temperature     transfer process    

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Correlations for estimating solar radiation using sunshine hours and temperature measurement in Osogbo

O. S. OHUNAKIN, M. S. ADARAMOLA, O. M. OYEWOLA, R. O. FAGBENLE

《能源前沿（英文）》 2013年 第7卷 第2期   页码 214-222 doi: 10.1007/s11708-013-0241-2

摘要： In this study, the global solar radiation on horizontal surface in Osogbo, Osun state, Nigeria was analyzed using 11-year data (1997–2007). Correlations using linear and quadratic expressions were developed to relate the global solar radiation on horizontal surface based on relative sunshine hours and temperature measurements for evaluating the monthly average daily global solar radiation. The calculated monthly clearness index values indicate that the prevailing weather condition in Osogbo is heavily overcast. All the developed quadratic correlations gave better correlation coefficients (0.834, 0.872 and 0.823 respectively) than the linear models. However, the Hargreaves and Samani related based quadratic model gave the best among the three developed quadratic expressions and is therefore suggested for estimating the monthly global radiation in this site and its surroundings.

关键词： global solar radiation     Hargreaves model     sunshine hour     ambient temperatures     Osogbo    

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Study on the Path of “Near-zero Emission” Coal-based Clean Energy Ecosystem Development

Zhang Yu-zhuo

《工程管理前沿（英文）》 2014年 第1卷 第1期   页码 37-41 doi: 10.15302/J-FEM-2014007

摘要： Developing a "near-zero emission" coal-based clean energy ecosystem bears great significance for the sustainable development of clean energy in China and the world at large. This article delves into the development strategy, implementation pathways and key priorities of China's "near-zero emission" coal-based clean energy ecosystem, and in turn proposes specific measures to underpin the development and implementation of such system.

关键词： near-zero emission     clean energy ecosystem     study on the path    

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Research and industrialization of near-net rolling technology used in shaft parts

Zhenghuan HU, Baoyu WANG, Zhenhua ZHENG

《机械工程前沿（英文）》 2018年 第13卷 第1期   页码 17-24 doi: 10.1007/s11465-018-0480-3

摘要：

Shaft part rolling is an efficient and green near-net shaping technology offering many advantages, including high production efficiency, high material utilization rate, high product quality, and excellent production environment. In this paper, the features of shaft part rolling are introduced along with the working principles of two main shaft part rolling technologies, namely, cross wedge rolling (CWR) and skew rolling (SR). In relation to this technology, some R&D achievements gained by the University of Science and Technology Beijing are summarized. Finally, the latest developments in shaft part rolling are presented, including SR steel balls, precise forming of camshaft blank by CWR, SR phosphorous copper balls at room temperature, and CWR hollow axle sleeve. Although the shaft part rolling technology has been widely used in China, it only accounts for about 15% of applicable parts at present. Nevertheless, this technology has broad application prospects.

关键词： cross wedge rolling     skew rolling     near-net rolling     shaft part    

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Special issue: Near-net shaping technology

Dequn LI, Dongming GUO, Qingxue HUANG, Yanchun LOU

《机械工程前沿（英文）》 2018年 第13卷 第1期   页码 1-2 doi: 10.1007/s11465-018-0497-7

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Human health ambient water quality criteria for 13 heavy metals and health risk assessment in Taihu Lake

《环境科学与工程前沿（英文）》 2022年 第16卷 第4期 doi: 10.1007/s11783-021-1475-6

摘要：

• The concentrations of 13 heavy metals in Taihu Lake were analyzed.

关键词： Heavy metals     Human health ambient water quality criteria     Taihu Lake     Health risk assessment     Contribution rate    

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Determining casting defects in near-net shape casting aluminum parts by computed tomography

Jiehua LI, Bernd OBERDORFER, Daniel HABE, Peter SCHUMACHER

《机械工程前沿（英文）》 2018年 第13卷 第1期   页码 48-52 doi: 10.1007/s11465-018-0493-y

摘要：

Three types of near-net shape casting aluminum parts were investigated by computed tomography to determine casting defects and evaluate quality. The first, second, and third parts were produced by low-pressure die casting (Al-12Si-0.8Cu-0.5Fe-0.9Mg-0.7Ni-0.2Zn alloy), die casting (A356, Al-7Si-0.3Mg), and semi-solid casting (A356, Al-7Si-0.3Mg), respectively. Unlike die casting (second part), low-pressure die casting (first part) significantly reduced the formation of casting defects (i.e., porosity) due to its smooth filling and solidification under pressure. No significant casting defect was observed in the third part, and this absence of defects indicates that semi-solid casting could produce high-quality near-net shape casting aluminum parts. Moreover, casting defects were mostly distributed along the eutectic grain boundaries. This finding reveals that refinement of eutectic grains is necessary to optimize the distribution of casting defects and reduce their size. This investigation demonstrated that computed tomography is an efficient method to determine casting defects in near-net shape casting aluminum parts.

关键词： near-net shape casting     aluminum parts     casting defects     low pressure die casting     die casting     semi-solid casting     computed tomography    

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Factors influencing near infrared spectroscopy analysis of agro-products: a review

Xiao XU, Lijuan XIE, Yibin YING

《农业科学与工程前沿（英文）》 2019年 第6卷 第2期   页码 105-115 doi: 10.15302/J-FASE-2019255

摘要：

The near infrared (NIR) spectroscopy technique has wide applications in agriculture with the advantages of being nondestructive, sensitive, safe and rapid. However, there are still more than 40 error sources influencing the robustness and accuracy of its calibration and operation. Environmental, sample and instrument factors that influence the analysis are discussed in this review, including temperature, humidity and other factors that introduce uncertainty. Error sources from livestock products, fruit and vegetables, which are the most common objects in the field of NIR analysis, are also emphasized in the second part. In addition, studies utilizing different instruments, spectral pretreatments, variable selection methods, wavelength ranges, detection modes and calibration methods are tabulated to illustrate the complications they introduce and how they influence NIR analysis. It is suggested that large scale of data with abundant varieties can be used to build a more robust calibration model, in order to improve the robustness and accuracy of the NIR analytical model, and overcome problems caused by confining analysis to too many uniform samples.

关键词： agro-product     error source     influence factor     near infrared spectroscopy    

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Hygroscopicity of ambient submicron particles in urban Hangzhou, China

Jiachen ZHANG, Lin WANG, Jianmin CHEN, Shengmao FENG, Jiandong SHEN, Li JIAO

《环境科学与工程前沿（英文）》 2011年 第5卷 第3期   页码 342-347 doi: 10.1007/s11783-011-0358-7

摘要： In this study, hygroscopicity of size-segregated ambient submicron particles in urban Hangzhou was studied from 28th December 2009 to 18th January 2010, using a hygroscopicity-tandem differential mobility analyzer (H-TDMA). The submicron particles in Hangzhou showed a minor hygroscopic growth at 73% relative humidity (RH), and then grew significantly between 77% and 82% RH. Monomodal distribution accounted for 90% for 30 nm particles, 17% for 50 nm particles, and less than 7% for particles larger than 50 nm at 82% RH. Deconvolution of the bimodal distribution indicated a less hygroscopic group and a more hygroscopic group, with the fraction of the more hygroscopic group increasing with the initial dry particle size and then remaining almost constant for accumulation mode particles. Our results imply that submicron particles in urban Hangzhou were almost entirely externally mixed, and the hygroscopic properties of ambient particles in urban Hangzhou were mainly a function of their size and chemical composition.

关键词： hygroscopicity     hygroscopic tandem differential mobility analyzer (H-TDMA)     submicron ambient particles     Hangzhou    

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Implementation of sinh method in integration space for boundary integrals with near singularity in potential

Guizhong XIE,Dehai ZHANG,Jianming ZHANG,Fannian MENG,Wenliao DU,Xiaoyu WEN

《机械工程前沿（英文）》 2016年 第11卷 第4期   页码 412-422 doi: 10.1007/s11465-016-0396-8

摘要：

As a widely used numerical method, boundary element method (BEM) is efficient for computer aided engineering (CAE). However, boundary integrals with near singularity need to be calculated accurately and efficiently to implement BEM for CAE analysis on thin bodies successfully. In this paper, the distance in the denominator of the fundamental solution is first designed as an equivalent form using approximate expansion and the original sinh method can be revised into a new form considering the minimum distance and the approximate expansion. Second, the acquisition of the projection point by Newton-Raphson method is introduced. We acquire the nearest point between the source point and element edge by solving a cubic equation if the location of the projection point is outside the element, where boundary integrals with near singularity appear. Finally, the subtriangles of the local coordinate space are mapped into the integration space and the sinh method is applied in the integration space. The revised sinh method can be directly performed in the integration element. A verification test of our method is proposed. Results demonstrate that our method is effective for regularizing the boundary integrals with near singularity.

关键词： computer aided engineering (CAE)     boundary element method (BEM)     near singularity     sinh method     coordinate transformation     integration space    

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Effect of ambient polycyclic aromatic hydrocarbons and nicotine on the structure of Aβ protein

《环境科学与工程前沿（英文）》 2023年 第17卷 第2期 doi: 10.1007/s11783-023-1615-2

摘要：

● B[a]P, nicotine and phenanthrene molecules altered the secondary structure of Aβ42.

关键词： Polycyclic aromatic hydrocarbons     Nicotine     toxicology     Aβ42 peptide     Alzheimer’s disease     Molecular dynamics simulations     Environmental pollution    

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标题 作者 时间 类型 操作

Chemisorption solid materials for hydrogen storage near ambient temperature: a review

Yiheng ZHANG, Shaofei WU, Liwei WANG, Xuefeng ZHANG

期刊论文

Evaluating the short-term effect of ambient temperature on non-fatal outdoor falls and road traffic injuries

期刊论文

Prediction of the theoretical and semi-empirical model of ambient temperature

Foued CHABANE,Noureddine MOUMMI,Abdelhafid BRIMA,Abdelhafid MOUMMI

期刊论文

Effects of ambient temperature on regulated gaseous and particulate emissions from gasoline-, E10- and

Rencheng Zhu, Jingnan Hu, Liqiang He, Lei Zu, Xiaofeng Bao, Yitu Lai, Sheng Su

期刊论文

Numerical investigation on side heat transfer enhancement in 300 kA aluminum reduction cell

WANG Changhong, ZHU Dongsheng, LEI Junxi, ZHOU Jiemin

期刊论文

Correlations for estimating solar radiation using sunshine hours and temperature measurement in Osogbo

O. S. OHUNAKIN, M. S. ADARAMOLA, O. M. OYEWOLA, R. O. FAGBENLE

期刊论文

Study on the Path of “Near-zero Emission” Coal-based Clean Energy Ecosystem Development

Zhang Yu-zhuo

期刊论文

Research and industrialization of near-net rolling technology used in shaft parts

Zhenghuan HU, Baoyu WANG, Zhenhua ZHENG

期刊论文

Special issue: Near-net shaping technology

Dequn LI, Dongming GUO, Qingxue HUANG, Yanchun LOU

期刊论文

Human health ambient water quality criteria for 13 heavy metals and health risk assessment in Taihu Lake

期刊论文

Determining casting defects in near-net shape casting aluminum parts by computed tomography

Jiehua LI, Bernd OBERDORFER, Daniel HABE, Peter SCHUMACHER

期刊论文

Factors influencing near infrared spectroscopy analysis of agro-products: a review

Xiao XU, Lijuan XIE, Yibin YING

期刊论文

Hygroscopicity of ambient submicron particles in urban Hangzhou, China

Jiachen ZHANG, Lin WANG, Jianmin CHEN, Shengmao FENG, Jiandong SHEN, Li JIAO

期刊论文

Implementation of sinh method in integration space for boundary integrals with near singularity in potential

Guizhong XIE,Dehai ZHANG,Jianming ZHANG,Fannian MENG,Wenliao DU,Xiaoyu WEN

期刊论文

Effect of ambient polycyclic aromatic hydrocarbons and nicotine on the structure of Aβ protein

期刊论文